Chapter 5 : Recording materials


5.1 Silver-halide materials44

Silver-halide recording materials for holography are interesting for many reasons. Silver halide was the first material used for recording holograms. It is also the most important material for holography in respect of its numerous scientific and artistic applications. In addition, it has high sensitivity in comparison with many other alternative materials. It can be coated on both film and glass, it can cover even very large formats, it can record both amplitude and phase holograms, it has high resolving power, and is easily available. But it has some drawbacks. It is absorptive, it has inherent noise and a limited linear response, it is irreversible, it needs wet processing, it creates printout problems in phase holograms, etc.

In our holographic multi-stereogram development we use silver-halide materials even if in the future photopolymer materials could be the most common.

5.1.1 Holographic film 6 47

Photographic materials for holography must meet specific requirements. This is essential with very high resolving power, since the dimensions of the structure of the interference pattern to be recorded are usually of the order of magnitude of the wavelength of the light used for exposure. A high speed is also desirable to allow short exposure time.

High resolving power and high speed are often incompatible properties, which makes it necessary to arrive at a compromise of the highest possible efficiency. The nature of the subject will determine whether the ideal solution of this problem will be slanted towards high speed or high resolving power.

High speed film means that the film is very sensitive to light, and we can take a picture with low intensity of light. This means physically that the size of grain of emulsion must be big and that the resolution will be low. The resolution is expressed in lines pr. millimetre.

There are a number of different types of filmplates and filmplates from different companies.

The filmplates that are chosen in this thesis is AGFA-GEVAERT Holotest, and have the number 10 E 75 and 8 E 75 HD.

These types of filmplate are made to be used with a red light emitting laser.

Film type Size of grain Resolution Emulsion thickness Sensitivity at 633 nm
  nm l/mm m J/cm2
10 E 75 90 3000 7 1
8 E 75 HD 35 5000 7 10

Figure 5-1 Film data from Holotest photographic materials

The emulsion thickness for these films is about 11 times the wavelength of the Helium-Neon laser ( 632,8nm). This type of hologram is a thick or volume hologram . What characterises a volume hologram is the depth of the image produced on the film plate. Thin holograms with emulsion thickness less than the wavelength of the laser have little or no depth.


Figure 5-2 Spectral sensitivity for 10 E 75 Figure 5-3 Spectral sensitivity for 8 E 75 HD

The holographic emulsion 8 E 75 HD and 10 E 75 are specially sensitised for wavelengths between 600 and 750 nm, and are intended for use with the He-Ne laser (633nm) and the ruby laser (694nm). The sensitivity for light of wavelengths around 500 nm (green light) is relatively bad. Thus we may use green light with low intensity during the hologram developing process.

Amplitude transmission is defined as the ratio between the amplitudes of a monochromatic plane wave before and after passing through the photographic emulsion.

This quantity T, is expressed as a function of the exposure shown in figure 5-4.
The light intensity is chosen so that the mean value of the transmission is in the linear region.
The optical density D is 0.6.

The blackening of photographic emulsion can be expressed with help of the optical density, D.
The speed or sensitivity of the film is given by DIN or ASA. Both of these are based on the linear part of the curve.

Figure 5-4 The characteristic curves for AGFA Holotest materials.

The relation between transmission T and optical density D is given by the equation

T = e -1.15 * D (5.1)

From the amplitude transmission curve we choose T from the linear part of the curve and get T= 0.5

With some manipulation we have

D = ln T /(-1.15) = 0.6

From the characteristic curve, shown in figure 5-4, we can see that D = 0.6 is in the non-linear part of the curve. The exposure of the filmplate will then be bad and the brightness of the image will not be very good.

What we want is a brighter image, and so we need a more exposed image. The result of a more exposed image is a over-exposed film plate. To remove the over-exposed material from the filmplate, we have to use a bleacher. The bleaching process transforms the hologram from an amplitude to a phase hologram. The phase hologram gives the best experimental results with D = 2.


Figure 5-5 Amplitude transmission T versus log exposure curves for AGFA Holotest materials

( It ) is the light intensity multiplied against the exposure time.

From figure 5-5 we get the approximate values of light intensities for T = 0.5 J/cm2 for a 10 E 75 filmplate, and for 10 J/cm2 for a 8 E 75 HD filmplate.

We can see from these results that the 8 E 75 HD need 20 times as much energy during the exposure as the 10 E 75 filmplate. That means that the exposure time for a 8 E 75 HD has to be 20 times longer.

5.1.2 The design angle for a holographic set-up49

A characteristic parameter of any holographic system is the design angle, i.e. the average angle at which the reference beam crosses the object beam at the filmplate. For an extended object close to the plate, there will be a range of such angles, and it is then safe to take the largest angle as the design angle. There are also other important parameters like the resolving power, the grain size of the optimum recording plate and the effective speed of the optimum recording plate.

The relationship between these parameters is relatively simple. If the reference and object beams cross the plate at angles v1 and v2 , we expect them to generate fringes of width d where

(5-2)

Thus the resolution of the system is of order d.



Figure 5-6 Line density for the film

After d is decided, one requires a photographic plate capable of recording fringes of this width, even though they may not have a very high contrast. Uncertainty in the contrast is a factor which must be allowed for, and these criteria then allow one to choose a suitable filmplate without an actual test. But it is possible to indicate a range of useful emulsions. Once the emulsion is chosen, its speed is fixed.

It is common to characterise emulsions by a factor p which is the number of lines pr. millimetre that the plate will record.

The exposed time goes up as p2 for moderate p, in accordance with the theory, since the number of resolvable points per unit area in two dimensions also goes up as p2.

In the case of very fine grain plates the penalty in practice may be even higher than indicated in the theory the exposure time can goes up as p4. There is also a heavy penalty in the form of stricter vibration stability requirements.

5.1.3 Film emulsion for transmission and rainbow holograms

The distance between two interference lines is given by:

(5.2a)

With the use of the trigonometric identity :

(5.2b) where v1+v2=U and v1= v2

If v1 and v2 is equal, the distance between two interference lines can be written as:

(5.2c)

Spatial frequencies are defined as : , and for U= 90o we get

(5-3)

The film chosen for the recording of transmission and rainbow hologram is AGFA-Gevaert holotest 10 E 75, which has a resolution of 3000 lines/mm, which is adequate for these holograms.

5.1.4 Film emulsion for reflection holograms

When recording reflection holograms, the reference and object beams illuminate the film on opposite sides. According to the theory for reflection holograms, the distance between the layers is 1/2 as shown in figure 5-7.


Figure 5-7 Interference lines in the film emulsion produced by plane waves.

The distance between the interference lines or planes is given by :

, where (5.4) using eq. (5.3)

and

, where the spatial frequencies is defined as :


The film chosen for reflection holograms is AGFA-Gevaert Holotest 8 E 75 HD, which has a resolution of 5000 lines/mm.

5.2 Non silver-halide materials 38 44

5.2.1 Dichromated gelatine

Dichromated gelatine is currently in widespread use because of its excellent holographic properties, including low scattering and high index modulation. The drawbacks of dichromated gelatine include the raw material's variability, complex wet processing, poor shelf-life, and environmental instability requiring hermetic sealing. In common with other non-silver halide materials, dichromated gelatine is usually sensitive only to UV and blue light. Recent research has made it possible to sensitise it to red laser light, though exposures are still long. The dichromated gelatine material has a rather low sensitivity of about 100 mJ/cm2 . Silver halide films are used when high exposure sensitivity and/or wide spectral sensitivity is needed, and when lower resolution and greater light scattering can be tolerated.

5.2.2 Du Pont photopolymer materials 20

Photopolymer materials can be used for recording phase holograms, where applications in mass-production of display holograms and optical elements are of main interest. Normally, the material has a short shelf-life and a rather limited refractive index change. The exposure for transmission holograms is about 5 mJ/cm2 and about 30 mJ/cm2 for reflection holograms. Diffraction efficiency can be as high as 60 % for a transmission hologram and 85 % for a reflection hologram, and the signal-to-noise ratio is about 90:1 for exposures which give the highest diffraction efficiency.

5.2.3 Photoresist materials

Photoresists are well-known from the electronic industry, where they are used in the production of circuit boards. In holography, they are employed mainly for the production of master plates for embossed holograms and for manufacturing holographic gratings. The photoresist process can be used for making transmission holograms only. If an embossed hologram is mirror-backed by using e.g. an aluminium coating process, it can be utilised in the reflection reconstruction mode as well. A typical photoresist for holography has a sensitivity of about 10 mJ/cm2. It is sensitive for UV and for visible light up to 500 nm.


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